Olivia Palermo Mango Winter catalog purple sequin one shoulder dress

Palermo sparkles in Mango's winter catalog. Photo courtesy of Mango

Although Olivia Palermo's run on the just-cancelled show "The City" might be coming to a screeching halt, it doesn't look like she's planning on stepping out of the spotlight anytime soon.

The stylish 24-year-old socialite-cum-reality villain is the star of Mango's new winter catalog, in which she strikes poses alongside her German-born model boyfriend Johannes Huebl.

"I love working with Johannes and the photographers love seeing the chemistry that exists between us," Palermo, who lives with Huebl in Brooklyn, said in a statement. "Also, working with Mango is like a dream, because it is a wonderful company."

In the series of images, shot by Txema Yeste at Barcelona's Hotel Palace, Palermo wears an asymmetrical purple sequined dress, a black party frock with a tulle overlay paired with a faux fur, a burgundy dress with a knotted neckline, and a white spaghetti-strap top tucked into a black skirt.

Like what you see? All the looks are in stores now.

Speaking of spaghetti, one of the more fantasy-driven images shows the waiflike Palermo and lanky Huebl with big plates of pasta in front of them. How very Madonna for Dolce!

Palermo's deep plum lip and relatively nude eyes by Jordi Fontanals add up to a more dramatic look than we're accustomed to seeing from her, while her Christoph Hasenbein-styled hair is straight, severe, and slicked back.

Olivia Palermo boyfriend Johannes Huebl Mango Winter catalog white tank top black skirt

Sitting pretty: Palermo and her boyfriend Johannes Huebl. Photo courtesy of Mango

What do you think of Palermo's images for Mango? Let us know in a comment below.

In related news, hear what "The City" star Whitney Port had to say about Palermo's plans to become a fashion designer.