Courtesy of Ann Taylor

Demi Moore is famous for many things: appearing naked while pregnant on the cover of Vanity Fair, marrying Ashton Kutcher (15 years her junior) and tweeting up a storm. Now the movie star is adding something else to her resume: her latest role as the new face of Ann Taylor. This partnership was a long time in the making as she told, "When I was a teenager and I moved to L.A., I remember going to the old Century City mall, and there was Ann Taylor. And it was a very prominent and memorable part of my youth and shopping experience." Although she wears high end labels like Lanvin, Prabal Gurung and Dior on the red carpet (Rachel Zoe is her stylist after all), Ann Taylor's latest collection suits her personal style which she defines as, "classic with a little bit of an edge." Demi Moore joins a long list of celebrities who have represented the brand in recent years including Heidi Klum, Milla Jovovich, Katie Holmes and Naomi Watts. What do you think of Demi's ad for Ann Taylor?

Take a peek in our gallery below to see other famous faces who have modeled for Ann Taylor: